Hybrid cellulose-poly(4-vinylpyridine) adsorbents produced via ATRP and their application to target polyphenols in winemaking, olive oil production and almond processing residues

نویسندگان

چکیده

Hybrid cellulose-poly(4-vinylpyridine) particles (MCC-P(4VP)) were synthesized via ATRP grafting and used as adsorbents to target polyphenols in residues derived from winemaking, olive oil production almond processing. These hybrid preserve good conditions be continuous sorption/desorption processes assessed for the retention of solvent mixtures ranging 0 100% water content. Other seven these assays, including three commercial resins further materials this research with 4VP. We show that 4VP based present a much higher average polyphenol broad range working conditions, namely concerning content extract. This behavior stems strong binding capacity pyridyl functional group towards many excels MCC-P(4VP) when hydrophobic interactions play minor role. also purification fractionation using simple steps. A fraction enriched malvidin-3-O-glucoside anthocyanin was obtained grape pomace. Fractions high isorhamnetin-3-O-rutinoside isolated almond. secoiridoids flavonoids produced mill wastewater while phenolic alcohols acids removed. results potential improve downstream processing increase biorefining efficiency, through direct handling organic extracts at concentration. has disclosed formation polymer population deviating expected homogeneous process grafting. The partition reactants between two regions phase could source some potentially interesting issues relevant monomers presenting H-bond capability, such Thus, future developments are possible designing here addressed, introduction molecular recognition features.

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ژورنال

عنوان ژورنال: Reactive & Functional Polymers

سال: 2021

ISSN: ['1381-5148', '1873-166X']

DOI: https://doi.org/10.1016/j.reactfunctpolym.2021.104930